Which of the following species can act as both a Bronsted acid and a Bronsted base?

Which one of the following is not a base?

Which of the following is not a conjugate acid-base pair?

Given below are two statements,one is labelled as Assertion $A$ and the other is labelled as Reason $R:$
Assertion $A :$ The amphoteric nature of water is explained by using Lewis acid/base concept.
Reason $R :$ Water acts as an acid with $NH_{3}$ and as a base with $H_{2}S$.
In the light of the above statements,choose the correct answer from the options given below:

The ammonium ion $(NH_4^+)$ is a/an ...........

The first and second dissociation constants of an acid $H_2A$ are $1.0 \times 10^{-5}$ and $5.0 \times 10^{-10}$ respectively. The overall dissociation constant of the acid will be